Preheat oven to 350°F. Line an 8x11-inch baking tray with foil, leaving some overhang on two opposite sides to use for lifting the bars out later.
In a large, heavy pan over low heat, gently melt 10 tablespoons unsalted butter, stirring until melted. Remove the pan from the heat.
Add 2 cups light brown sugar to the melted butter and stir until combined. Let the mixture cool for about 1 minute.
In a small bowl, beat 3 eggs until blended. Stir the beaten eggs and 1 teaspoon pure vanilla extract into the butter-sugar mixture until combined.
Sift 3 cups all-purpose flour, 1 teaspoon baking powder, and a large pinch salt together, then sift the mixture over the wet ingredients. Stir only until the dry ingredients are just incorporated—do not overmix.
Fold in ½ cup chopped walnuts and 1 cup semisweet chocolate chunks until evenly distributed.
Pour the batter into the prepared pan and spread it into an even layer.
Bake for 25 minutes, or until the top is just firm (a toothpick inserted near the center should come out with moist crumbs, not wet batter).
Cool in the baking tray until firm enough to lift. Use the foil overhang to lift the blondies onto a wire rack and cool completely. Remove the foil and cut into squares.