Line an 8x8 or 9x9 pan with parchment paper, leaving excess on two opposite sides to act as handles for easy removal.
In a large bowl, combine 1 cup melted and slightly cooled unsalted butter and 1 1/2 cups creamy peanut butter. Stir or beat until smooth and uniform.
Add 1 1/2 cups powdered sugar to the butter–peanut butter mixture and mix until incorporated. Add 2 cups graham cracker crumbs and stir until the mixture is evenly combined and holds together.
Transfer the mixture to the prepared pan. Press it firmly and evenly into the bottom of the pan with the back of a spatula or your hands, then smooth the top.
Place 1 1/2 cups chopped chocolate and 1/4 cup creamy peanut butter in a microwave-safe bowl. Microwave in 20–30 second intervals, stirring well between each interval, until the chocolate and peanut butter are completely melted and the mixture is smooth. (Alternatively, melt together in a double boiler, stirring until smooth.)
Pour the melted chocolate–peanut butter mixture over the pressed base and spread evenly with a spatula. Sprinkle 1/4 cup chopped roasted peanuts over the top.
Chill the bars in the refrigerator for at least 2 hours, or until firm. Use the parchment handles to lift the slab from the pan and cut into bars before serving.