Preheat the oven to 350°F (175°C). Line a 12- to 16-cup muffin tin with paper liners and set aside.
Make the streusel: in a small bowl combine 3/4 cup all-purpose flour, 1/2 cup packed brown sugar, and 1 teaspoon cinnamon. Add the 6 tablespoons cold, cubed butter and use your fingers or a pastry cutter to work the butter into the dry ingredients until the mixture is crumbly and pea-sized. Set the streusel aside.
In a large mixing bowl whisk together 1/2 cup melted butter, 1/2 cup real maple syrup, 2 teaspoons vanilla extract, 1/2 cup buttermilk, 1/2 cup plain Greek yogurt, and 2 eggs until smooth and homogenous.
In a separate bowl whisk together 2 cups all-purpose flour, 2 1/2 teaspoons baking powder, 1/2 teaspoon cinnamon, and 1/2 teaspoon kosher salt.
Add the dry ingredients to the wet ingredients and stir just until combined; do not overmix. Fold in 1 cup semi-sweet chocolate chips.
Divide half of the batter evenly among the prepared muffin cups (about half-full or 3/4 full depending on cup size). Evenly sprinkle about one-third of the streusel over this first layer of batter.
Spoon the remaining batter over the streusel layer, dividing it evenly among the cups. Top each muffin with the remaining streusel, dividing it evenly.
Place the filled muffin tin on a baking sheet for stability and transfer to the preheated oven. Bake 25–30 minutes, or until a toothpick inserted into the center of a muffin comes out clean or with just a few moist crumbs.
Remove the muffins from the oven and let them cool in the pan for 5–10 minutes, then transfer to a wire rack to cool slightly. Serve warm or at room temperature.